化工学院黄文欢团队近期在《Angew Chem.》《Adv. Sci.》等杂志上发表一系列研究成果

2023-07-13 08:57 文、图/化工学院 点击:[]

近期,我校化学与化工学院黄文欢团队围绕杂化多孔微纳结构的精确构造及能量转换存贮性能的调控方面取得了多项重要进展,连续在国际顶级期刊Angew Chem.Int. Ed.、Advanced Science、Carbon Energy等期刊上发表一系列研究论文。

【成果1】高密度原子CoFe掺杂多级孔吸波材料的设计及纳米涡旋偶极及磁畴的精确构造

黄文欢课题组与复旦大学车仁超教授合作设计低CoFe含量的含能MOF(金属三氮唑)前驱体,通过三氮唑400度左右的“爆炸”反应可以成功合成具有超低金属负载、超低密度的具有多级孔结构的CoFe掺杂三维碳海绵材料。实现对金属原子级分散、材料介电性能、耦合性能、阻抗匹配等的可控调控。

文章捕获了材料在不同温度下(400、600、800、1000oC)的产物,通过同步辐射、洛伦兹电镜,结合理论计算,揭示了材料随着温度的升高其多孔碳基底孔结构从大孔、介孔到微孔、纳米孔的演变,以及在基底上金属从团簇状态向单原子状态的演变、原子之间的相互作用,这些微观的原子及孔结构诱导了体系内纳米涡旋极化及涡旋磁畴的产生。最终实现了该材料体系的吸收强度、X/Ku波段的全吸收的双重性能调控。该成果发表于《Adv. Sci.》期刊上。

【成果23D MOF基膜原位生成富含LiF的Janus异质结构SEI稳定固态Li金属电池

黄文欢课题组与苏庆梅教授、扬州大学庞欢教授合作构建了离子液体限域MOF(金属咪唑)/聚合物三维多孔Janus膜,并在充放电循环过程中原位形成了富含LiF/Li3N的固态电解质界面(SEI)膜。此三维Janus膜具有快速的锂离子传输通道、优异的室温离子电导率(8.17×10-4S cm-1)和高的锂离子迁移数(0.82)。该复合电解质隔膜具有高热稳定性和机械强度的膜用于固态LiǁLiFePO4和LiǁNCM-811电池,甚至在软包电池中均显示出优异的倍率性能和超长的寿命。

文章详细的通过冷冻透射电镜对SEI中原位形成的LiF和Li3N纳米晶体以及锂枝晶的沉积进行了可视化监测,并对电池充放电过程中结构演变进行了理论模拟和动力学分析,揭示了电池充放电过程中的界面行为及机理。此工作为新型MOF基固态电解质的构建提供了一种新的思路和方法。该成果发表于《AngewChem. Int. Ed.》期刊上。

【成果3】单原子高价态Mo“陷阱”捕获电子诱导电荷聚集促进光催化产氢

黄文欢课题组与阿卜杜拉国王科技大学张华彬、Magnus Rueping教授合作,将高氧化态的Mo原子作为电子陷阱,以单原子形式植入Cd0.5Zn0.5S晶格中,降低了CZS的带隙并可以成功捕获光生电子,增强自由基数量。3.11 wt% Mo负载的CZS@Mo表现出了良好的光催化析氢性能(λ>420 nm)及稳定性。

文章详细通过瞬态吸收光谱监测了CZS和CZS @Mo的光生电子动力学行为,证实了Mo电子“陷阱”对电子-空穴复合的抑制作用。此外,DFT理论计算表明Mo原子周围的高电子密度,反应历程的吸附自由能解释了Mo位点的良好催化动力学,证实了Mo原子的电子捕获效应及其在光催化析氢中的反应机理。本文的研究结果为可控设计和制备具有良好应用前景的单原子光催化制氢催化剂提供了重要的理论依据。该成果发表于《AngewChem. Int. Ed.》期刊上。

【成果4】综述论文:面向碳中和构筑非均相催化剂催化转化二氧化碳为羧酸的研究进展

英雄联盟电竞官网(中国)有限公司官网,黄文欢教授、阿卜杜拉国王科技大学张华彬教授,中国石油大学智林杰教授,爱尔兰三一学院Max García-Melchor教授,北京化工大学于乐教授,清华大学王定胜教授共同总结了非均相催化剂用于CO2制备羧酸化合物的构筑策略,为活化,转化二氧化碳为羧酸等高附加值产物提供了明确的指导和重要参考。本文首先分别从光,电,热三个方面阐述了相应领域催化的机理过程,羧酸产物的类型和商业价值,以及目前取得的研究进展。其次从复合催化剂,杂原子参杂,形貌调控、表面功能化四个方面系统总结分析了非均相催化剂的合成,调控策略,强调了催化位点中配位环境,电子效应,空间效应等对其活性的影响,以及催化剂结构与活性的内在构效关系。最后,展望了CO2制备羧酸化合物面临的挑战以及未来的研究方向,为推动CO2的利用和羧酸化学品的可控制备提供了重要的启示。该成果发表于《CarbonEnergy》期刊上。

【成果5】燃烧法诱导含能MOF向金属氧化物多级孔碳材料的结构及吸波性能调控

黄文欢课题组与南京理工大学吴凡教授合作,以含能金属有机骨架为材料,通过燃烧的原位转化工艺,成功制备了具有超高多孔微纳结构和均匀分散的CoFe单元的三维磁性分子海绵(表示为CoFe@PCS)。其独特的框架结构和集成的磁介电元件使其具有高效的微波吸收。在厚度为2.57 mm处,CoFe@PCS的最小反射损耗为−70.10 dB,有效吸收带宽为8.64 GHz。更重要的是,深入剖析了磁性海绵内部的损耗机制和能量耗散,揭示了弛豫主导的介质损耗和介电-磁协同作用。这项工作为高性能吸收体的目标设计和制造提供了一种巧妙的方法。该成果发表于《Advanced Composites and Hybrid Materials》期刊上。

【成果6】主客体框架原位水热合成超高性能POMOF@CoNi-水滑石超级电容器电极材料

张亚男、黄文欢教授,通过主客体效应水热合成杂多酸掺杂的-铜基金属有机骨架,通过水热刻蚀的方法构造了POMOF@CoNi-LDH纳米片结构。材料类因其超高的比表面积、丰富的电化学活性位点和,作为超级电容器电极材料,在1A·g-1时表现出了333.61 mAh·g-1的高比容量。在混合超级电容器中POMOF@CoNi-LDH/活性炭(AC),能量密度高达80.8 Wh·kg-1、功率密度750.7 W·kg-1。更重要的是,,在10A·g-1条件下充放电5000次后,材料表现出优异的电容保持(79%),本文提供了一个高性能储能电极材料的合成方法及策略。该成果以OutsideFrontCover发表于《Chin. J. Chem.》期刊上。

【成果7】CoNi掺杂中空碳化钼球的可控合成及电磁波吸收性能的调控

黄文欢教授团队,通过设计双金属CoNi掺杂的晶态杂化金属咪唑框架,利用化学刻蚀及热处理的方法原位构造了超薄的中空CoNi掺杂的碳化钼球,成功的调控了材料的介电损耗、磁耦合和阻抗匹配性能。材料在负载量为15wt %时,表现出了最优的电磁波吸收性能RLmin=-60.05 dB。该成果受邀发表于《Chin. J. Chem.》期刊上。

【作者简介】

黄文欢,陕西省“科学家+工程师”创新团队首席科学家、陕西省科技新星,近年来主持国家项目2项、省部级各类科研项目7项、教学项目2项,获得陕西省高校科学技术奖一等奖1项,陕西省人才计划项目2项。在Angew Chem. Int. Ed.、Nano-Micro Letters、Carbon Energy、Matter、Journal of Materials Chemistry A、Energy & Environmental Materials、Chemical Engineering Journal、Materials Chemistry Frontiers、Chemical Communications、Carbon、Journal of Power Sources、Nanoscale、Chemistry-A European Journal、Inorganic Chemistry等国际期刊上发表SCI论文50余篇,其中受邀撰写综述6篇,高被引论文7篇,热点论文2篇,授权国家发明专利4项。曾受邀请在国内外学术会议上作报告10余次,媒体转载相关研究成果20余次。组织学生参加“挑战杯”课外学术科技竞赛获得省级二等奖2项、三等奖1项,获得陕西省第六届研究生创新成果展省级一等奖1项,省级创新基金1项;培养研究生获得“优秀毕业生”、“优秀硕士毕业论文”、“国家奖学金”、“研究生高水平科研成果奖励”等。

教师网页:https://hg.sust.edu.cn/info/1237/5653.htm

【团队近年来发表文章】

  1. 2023年

  2. W. Huang,*X. Zhang, J. Chen, Q. Qiu, Y. Kang, K. Pei, S. Zuo, and R. Che*, High-density Nanopore Confined Vortical Dipoles and Magnetic Domains on Hierarchical Macro/Meso/Micro/Nano Porous Ultra-Light Graphited Carbon for Adsorbing Electromagnetic Wave,Advanced Science, 10.1002/advs.202303217.(2022影响因子:15.1)

  3. X. Zhang, Q. Su*, G. Du, B. Xu, S. Wang, Z. Chen, L. Wang,W. Huang*, H. Pang*, Stabilizing Solid-state Lithium Metal Batteries through In Situ Generated Janus-heterarchical LiF-rich SEI in Ionic Liquid Confined 3D MOF/Polymer Membranes,Angew Chem. Int. Ed.,2023, e202304947.(2022影响因子:16.6)

  4. W. Huang, C. Su, C. Zhu, T. Bo, S. Zuo, W. Zhou, Y. Ren, Y. Zhang, J. Zhang, M. Rueping*, H. Zhang*,Isolated Electron Trap-Induced Charge Accumulation for Efficient Photocatalytic Hydrogen Production,Angew Chem., Int. Ed.,2023, e202304634.(VIP paper)(2022影响因子:16.6)

  5. X. Zhang,W. Huang*,L. Yu, M. García-Melchor, D. Wang, L. Zhi* and H. Zhang* Enabling Heterogeneous Catalysis to Achieve Carbon Neutrality: Directional Catalytic Conversion of CO2into Carboxylic Acids,Carbon Energy,2023,e362.(2022影响因子:20.5)

  6. M. Sun, W. Cao, P. Zhu, Z. Xiong, C. Chen, J. Shu*,W. Huang*, Fan Wu*, Thermally tailoring magnetic molecular sponges through self-propagating combustion to tune magnetic-dielectric synergy towards high-efficiency microwave absorption and Attenuation,Advanced Composites and Hybrid Materials,2023, 6: 54.(2022影响因子:20.1)

  7. H. Ruan, L. Zhang*, S. Li, K. Wang,W. Huang,S. Guo*, Carbon Polyhedra Encapsulated Si Derived from Co-Mo Bimetal MOFs as Anode Materials for Lithium-Ion Batteries,Journal of Materials Science & Technology,2023, 159: 91–98.(2022影响因子:10.9)

  8. Y. Li, X. Jin*, Y. Ma, L. Ma, J Liu, P. Zhu, Z. Deng, H. Zhou, W Chen,W. Huang*,Functional decoration on a regenerable bifunctional porous covalent organic framework probe for the rapid detection and adsorption of copper ions,Rare Metals,In press.(2022影响因子:8.8)

  9. Y. Zhang, J. Chen, F. Razq, C. Su, X. Hou,W. Huang*,and H. Zhang*, Polyoxometalate-incorporated host-guest framework derived layered double hydroxide composites for high-performance hybrid supercapacitor,Chinese Journal of Chemistry,2023,41, 75-82.(杂志封面Outside Front Cover)(2022影响因子:5.4)

  10. X. Yang, W. Gao, J. Chen, X. Lu, D. Yang, Y. Kang, Q. Liu, Y. Qing, andW. Huang*, Co-Ni Electromagnetic Coupling in Hollow Mo2C/NC Sphere for Enhancing Electromagnetic Wave Absorbing Performance,Chinese Journal of Chemistry,2023, 41, 64-74.(邀稿,2022影响因子:5.4)

  11. J. Gu, Q. An, J. Chen, Y. He,W. Huang*, Preparation and Responsive Performance study of AuNPs/RGO-MoO2/GCE Composite Modified Electrodes based on its High Sensitivity to Acetaminophen and Dopamine,Inorganic Chemistry Communications,2023, 147, 110282.(2022影响因子:3.8)

  12. Y.Kang, X. Sun, Y. Wang, Y. Zhang, W. Huang*,Design and Synthesis of Copper-Based Simulated Enzyme Induced by Nitrogen Oxidation Ligand and Study of Its Activity.Chinese Journal of Structural Chemistry,2023, 42, 100046.(邀稿,2022影响因子:2.2)

  13. 2022年

  14. W. Huang*, Q. Qiu, X. Yang, S. Zuo, J. Bai, H. Zhang*, K. Pei and R. Che*, Ultrahigh Density of Atomic CoFe-Electron Synergy in Noncontinuous Carbon Matrix for Highly Efficient Magnetic Wave Adsorption.Nano-Micro Letters,2022, 14(1): 96.(2022影响因子:26.6)

  15. C. Feng, Y. Ren, F. Razq,W. Huang*, H. Zhang*, An innovative and ingenious strategy to construct single-atom catalyst for photocatalytic methane conversion,Matter,2022,5, 3086–3111.(2022影响因子:18.9)

  16. W. Huang, T. Bo, S. Zuo, Y. Wang, J. Chen, S. Ould‐Chikh, Y. Li, W. Zhou*, J. Zhang, H. Zhang*, Surface decorated Ni sites for superior photocatalytic hydrogen production,Susmat,2022, 1-10.(邀稿,2022影响因子:28.4)

  17. W. Huang*, W. Gao, S. Zuo, L. Zhang, K. Pei, P. Liu and R. Che*, and H. Zhang*, Hollow MoC/NC Sphere for Electromagnetic Wave Attenuation: Direct Observation of Interfacial Polarization on Nanoscale Hetero-interfaces.Journal of Materials Chemistry A,2022, 10: 1290-1298.(杂志封面Outside Front Cover)(高被引论文)(2022影响因子:11.9)

  18. P. Li, Z. He, X. Li,W. Huang*, and X. Lu*, Fullerene-Intercalated Graphitic Carbon Nitride as a High-Performance Anode Material for Sodium Ion Batteries.Energy & Environmental Materials,2022, 5: 608–616.(邀稿,2022影响因子:15)

  19. Y. Zhang, J. Chen, C. Su, K. Chen, H. Zhang, Y. Yang,W. Huang*, Enhanced ionic diffusion interface in hierarchical metal-organic framework@layered double hydroxide for high-performance hybrid supercapacitors,Nano Research,2022, 15(10), 8983-8990.(2022影响因子:9.9)

  20. W. Huang*, J. Chen, W. Gao, L. Wang, P. Liu*, Y. Zhang, Z. Yin, Y. Yang, “Host-Guest” crystalline Mo/Co-framework induced phase-conversion of MoCx in carbon hybrids for regulating absorption of electromagnetic wave,Carbon,2022, 197: 129-140.(2022影响因子:10.9)

  21. W. Huang*, S. Wang, X. Yang, X. Zhang, Y. Zhang, K. Pei, R. Che*, Temperature induced transformation of Co@C nanoparticle in 3D hierarchical core-shell nanofiber network for enhanced electromagnetic wave adsorption,Carbon,2022, 195: 44-56.(2022影响因子:10.9)

  22. W. Huang*, Z. Chen, H. Wang, L. Wang, H. Zhang, and H. Wang, Sponge-like hierarchical porous carbon decorated by Fe atoms for high-efficient sodium storage and diffusion.Chemical Communications,2022, 58(28), 4496-4499.(2022影响因子:4.9)

  23. Y. Zhang, C. Su, J. Chen,W. Huang*and R. Lou, Recent progress of transition metal-based biomass-derived carbon composites for supercapacitor,Rare metals,2022,10.1007/s12598-022-02142-7.(2022影响因子:8.8)

  24. Z. He, Z. Zhou, P. Wei, T. Xu, J. Han, K. Huang, K. Guo*,W. Huang*, T. Akasaka, X. Lu*, Fullerene-Derived Porous and Defective N-Doped Carbon Nanosheets as Advanced Trifunctional Metal-Free Electrocatalysts,Chemistry - An Asian Journal,2022, 202200994.(2022影响因子:4.1)

  25. 2021年

  26. W. Huang*, X. Li, X. Yang*, H. Zhang, P. Liu, Y. Ma, and X. Lu, CeO2-embedded mesoporous CoS/MoS2as highly efficient and robust oxygen evolution electrocatalyst.Chemical Engineering Journal,2021, 420: 127595.(2022影响因子:15.1)

  27. W. Huang*, X. Li, X. Yang*, X. Zhang, H. Wang, The recent progress and perspectives on the metal- and covalent- organic frameworks based solid-state electrolytes for lithium-ion batteries.Materials Chemistry Frontiers,2021, 5 (9): 3593-3613.(邀稿,2022影响因子:7.0)

  28. W. Huang*, X. Li, X. Yang, H. Zhang, F. Wang, J. Zhang*. High-Efficient Electrocatalyst for Overall Water Splitting: Mesoporous CoS/MoS2with Hetero-Interface.Chemical Communications,2021, 57: 4847-4850.(2022影响因子:4.9)

  29. W. Huang*, Q. Li, D. Yu, Y. Tang, D. Lin, F. Wang*, J. Zhang*, Hybrid Zeolitic Imidazolate Frameworks for Promoting Electrocatalytic Oxygen Evolution via a Dual-Site Relay Mechanism.Inorganic Chemistry,2021, 60(5): 3074-3081.(2022影响因子:4.6)

  30. X. Yang, Y. Yan, W. Wang, Z. Hao, W. Zhang*,W. Huang*, Y. Wang, A 2-Fold Interpenetrated Nitrogen-Rich Metal–Organic Framework: Dye Adsorption and CO2Capture and Conversion.Inorganic Chemistry.2021,60(5): 3156-3164(2022影响因子:4.6)

  31. W. Huang*, X. X. Zhang and Y. N. Zhao, Recent progress and perspectives on the structural design on metal-organic zeolite (MOZ) frameworks.Dalton Transactions,2021, 50: 15-28.(邀稿,2022影响因子:4.0)

  32. Y. Zhang, J. Chen, C. Su,W. Huang*, A multifunctional cadmium-based metal-organic framework from a tricarboxylate ligand showing sensing and sensitization.Journal of Solid State Chemistry,2021, 302: 122407.(2022影响因子:3.3)

  33. C. Zuo, F. Zhao, Z. Tang, L. Zhang, Q. Niu, G. Cao, L. Zhao,W. Huang*, and P. Zhao*, Bi2O3gated Fe3O4@ZrO2core/shell drug delivery system for chemo/ionic synergistic therapeutics.Journal of Solid State Chemistry,2021, 303: 122489.(2022影响因子:3.3)

  34. 2020年

  35. P. Liu*, S. Gao, Y. Wang, Y. Huang, W. He,W. Huang, J. Luo, Carbon nanocages with N-doped carbon inner shell and Co/N-doped carbon outer shell as electromagnetic wave absorption materials,Chemical Engineering Journal,2020, 381: 122653.(高被引论文)(2022影响因子:15.1)

  36. T. Xu, W. Shen,W. Huang*, and X. Lu*. Fullerene Micro/Nanostructures: Controlled Synthesis and Energy Applications.Materials Today Nano,2020, 11:100081.(邀稿,2022影响因子:10.3)

  37. W. Huang*, X. Zhang, Y. Zhao, J. Zhang, and P. Liu*, Hollow N-doped carbon polyhedrons embedded Co and Mo2C nanoparticles for high-efficiency and wideband microwave absorption.Carbon,2020, 167: 19-30.(高被引论文,热点论文)(2022影响因子:10.9)

  38. P. Liu*, S. Gao, Y. Wang, F. Zhou, Y. Huang,W. Huang*, and N. Chang, Core-shell Ni@C encapsulated by N-doped carbon derived from nickel-organic polymer coordination composites with enhanced microwave absorption.Carbon,2020, 170: 503-516.(高被引论文,热点论文)(2022影响因子:10.9)

  39. P. Liu*, S. Gao,W. Huang*, J. Ren, D. Yu, and W. He, Hybrid zeolite imidazolate framework derived N-implanted carbon polyhedrons with tunable heterogeneous interfaces for strong wideband microwave attenuation.Carbon,2020, 159: 83-93.(高被引论文)(2022影响因子:10.9)

  40. W. Huang*, X. Li, D. Yu, X. Yang, L. Wang, P. Liu, and J. Zhang, CoMo-bimetallic N-doped porous carbon materials embedded with highly dispersed Pt nanoparticles as pH-universal hydrogen evolution reaction electrocatalyst.Nanoscale,2020, 12: 19804-19813.(2022影响因子:6.7)

  41. T. Xu, D. Yu, Z. Du,W. Huang*, and X. Lu, Two-Dimensional Mesoporous Carbon Materials Derived from Fullerene Microsheets for Energy Applications.Chemistry-A European Journal,2020, 26: 10811.(2022影响因子:4.3)

  42. K. Zhong, R. Yang, W. Zhang*, Y. Yan, X. Gou,W. Huang*,and Y.-Y. Wang, Zeolitic Metal Cluster Carboxylic Framework for Selective Carbon Dioxide Chemical Fixation through the Superlarge Cage.Inorganic Chemistry,2020, 59: 3912-3918.(2022影响因子:4.6)

  43. Y. Zhang*,Y. Zhang, L. Li, J. Chen, P. Li,W. Huang*. One-step in situ growth of high-density POMOFs films on carbon cloth for the electrochemical detection of bromate.Journal of Electroanalytical Chemistry,2020, 861: 113939.(2022影响因子:4.5)

    (核稿:黄文欢 编辑:赵诚)

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